The title dinitrosyl iron diphosphane complex, [Fe(NO)(2)(C(18)H(12)Cl(3)P)(2)] or Fe(NO)(2)L(2) [L = P(C(6)H(4)-p-Cl)(3)] belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as dinitrosyl iron compounds (DNICs). The iron atom is tetra-hedrally coordinated by two phosphane ligands and two NO groups with Fe-N-O bond angles of 178.76â (15) and 177.67â (14)°.
Dinitro-sylbis[tris-(4-chloro-phen-yl)phosphane]iron.
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作者:Jones Myron W, Powell Douglas R, Richter-Addo George B
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jan 22; 67(Pt 2):m247 |
| doi: | 10.1107/S1600536811001693 | ||
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