Δ-Bis[(S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato-κ(2) N,O (1)](1,10-phenanthroline-κ(2) N,N')ruthenium(III) hexa-fluorido-phosphate.

The title compound, [Ru(C(12)H(14)NO(2))(2)(C(12)H(8)N(2))]PF(6) crystallizes in the tetra-gonal Sohnke space group P4(1)2(1)2. The two bidentate chiral salicyloxazoline ligands and the phenanthroline co-ligand coordinate to the central Ru(III) atom through N,O and N,N atom pairs to form bite angles of 89.76†(15) and 79.0†(2)°, respectively. The octa-hedral coordination of the bidentate ligands leads to a propeller-like shape, which induces metal-centered chirality onto the complex, with a right-handed (Δ) absolute configuration [the Flack parameter value is -0.003†(14)]. Both the complex cation and the disordered PF(6) (-) counter-anion are located on twofold rotation axes. Apart from Coulombic forces, the crystal cohesion is ensured by non-classical C-H⋯O and C-H⋯F inter-actions.