In the title compound, C(24)H(29)F(2)NO(4), which crystallizes in the ortho-rhom-bic Pca2(1) space group with Z = 4, the 1,4-di-hydro-pyridine ring adopts a distorted boat conformation, while the cyclo-hexene ring is in a distorted half-chair conformation. In the crystal, the mol-ecules are linked by N-Hâ¯O and C-Hâ¯O inter-actions, forming supra-molecular chains parallel to the a axis. These chains pack with C-Hâ¯Ï inter-actions between them, forming layers parallel to the (010) plane. The cohesion of the crystal structure is ensured by van der Waals inter-actions between these layers. Hirshfeld surface analysis shows the major contributions to the crystal packing are from Hâ¯H (56.9%), Fâ¯H/Hâ¯F (15.7%), Oâ¯H/Hâ¯O (13.7%) and Câ¯H/Hâ¯C (9.5%) contacts.
Synthesis, characterization, crystal structure and Hirshfeld surface analysis of isobutyl 4-[4-(di-fluoro-meth-oxy)phen-yl]-2,6,6-trimethyl-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carboxyl-ate.
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作者:Yıldırım Sema Ãztürk, Akkurt Mehmet, Ãetin Gökalp, ÅimÅek Rahime, Butcher Ray J, Bhattarai Ajaya
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2023 | 起止号: | 2023 Nov 10; 79(Pt 12):1132-1136 |
| doi: | 10.1107/S2056989023009623 | ||
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