Crystal structure of di-μ-chlorido-bis-(chlorido-{N(1),N(1)-diethyl-N(4)-[(pyridin-2-yl-κN)methyl-idene]benzene-1,4-di-amine-κN(4)}mercury(II)).

The title dinuclear mercury(II) complex, [Hg(2)Cl(4)(C(16)H(19)N(3))(2)], synthesized from the pyridine-derived Schiff base (E)-N(1),N(1)-diethyl-N(4)-[(pyridin-2-yl)methyl-idene]benzene-1,4-di-amine (DPMBD), has inversion symmetry. The five-coordinated Hg(II) atoms have distorted square-pyramidal stereochemistry comprising two N-atom donors from bidentate chelate BPMBD ligands and three Cl-atom donors, two bridging and one monodentate. The dihedral angle between the benzene and the pyridine rings in the BPMBD ligand is 7.55†(4)°. In the crystal, the dinuclear mol-ecules are linked by weak C-H⋯Cl hydrogen bonds, forming zigzag ribbons lying parallel to [001]. Also present in the structure are π-π inter-actions between benzene and pyridine rings [minimum ring-centroid separation = 3.698†(8)†à ].