(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(di-phenyl-phosphan-yl)benzyl-idene]amino}-ethan-1-amine)-platinum(II) dinitrate methanol disolvate.

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作者:Jurisinec Ashley, Zhang Yingjie, Aldrich-Wright Janice R
The title compound, [Pt(C(14)H(12)N(2))(C(21)H(21)N(2)P)](NO(3))(2)·2CH(3)OH, is a platinum(II) complex, which crystallizes in a monoclinic (P2(1)/c) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(di-phenyl-phosphan-yl)benzyl-idene]amino}-ethan-1-amine ligand. The structure reveals both intra- and inter-molecular π-stacking inter-actions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent mol-ecules.

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