The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41â (5)°. The two meth-oxy groups at the meta positions of the trimeth-oxy-benzene group are almost coplanar with the ring [C-O-C-C = 1.62â (16) and 178.33â (10)°], whereas the third meth-oxy group, at the para position, is (+)-synclinal with the ring. In the crystal, mol-ecules are linked by N-Hâ¯O and bifurcated O-Hâ¯(N,O) hydrogen bonds, as well as weak C-Hâ¯O inter-actions, into sheets lying parallel to the ac plane. A C-Hâ¯Ï inter-action also occurs.
(E)-4-Hy-droxy-N'-(3,4,5-trimeth-oxy-benzyl-idene)benzohydrazide.
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作者:Horkaew Jirapa, Chantrapromma Suchada, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Nov;67(Pt 11):o2985 |
| doi: | 10.1107/S1600536811041535 | ||
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