In the isoquinoline ring system of the title mol-ecule, C(22)H(20)N(2)O(5), the N-heterocyclic ring is in a half-boat conformation. The dioxa-2-aza-spiro ring is essentially planar [maximum deviation = 0.026â (1)â à ] and forms dihedral angles of 22.53â (5) and 64.46â (5)° with the benzene and phenyl rings, respectively. The mol-ecular structure is stabilized by a weak intra-molecular C-Hâ¯O hydrogen bond, which generates an S(7) ring motif. In the crystal, mol-ecules are linked via weak inter-molecular C-Hâ¯O and C-Hâ¯N hydrogen bonds into layers parallel to (102).
1-Benzyl-5-meth-oxy-2',3-dimethyl-4,6-dioxa-2-aza-spiro-[bicyclo-[3.2.0]hept-2-ene-7,4'-isoquinoline]-1',3'(2'H,4'H)-dione.
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作者:Fun Hoong-Kun, Quah Ching Kheng, Huang Chengmei, Yu Haitao
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jun 1; 67(Pt 6):o1311-2 |
| doi: | 10.1107/S160053681101600X | ||
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