The conformation of the N-H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichloro-phen-yl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, but in contrast to the anti conformation observed with respect to the 3-methyl substituent in 2,2-dichloro-N-(3-methyl-phen-yl)acetamide. The bond parameters in the title compound are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. The mol-ecules of the title compound are linked into chains through N-Hâ¯O and C-Hâ¯O hydrogen bonding.
2,2-Dichloro-N-(2,3-dimethyl-phen-yl)acetamide.
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作者:Gowda B Thimme, Svoboda Ingrid, Foro Sabine, Paulus Helmut, Fuess Hartmut
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2007 | 起止号: | 2007 Dec 12; 64(Pt 1):o234 |
| doi: | 10.1107/S1600536807064550 | ||
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