The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolate ligand and two bridging trimethyl-silanolate anions in a distorted tetra-hedral geometry. The dihedral angle between the benzotriazole ring system and the benzene ring is 19.83â (5)°. The tert-pentyl groups are disordered over two orientations with refined site-occupancy ratios of 0.858â (4):0.142â (4) and 0.665â (6):0.335â (6).
Bis(μ-trimethyl-silanolato-κO:O)bis-{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolato-κN,O]zinc}.
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作者:Lee Hwi Hyun, Go Min Jeong, Park Ka Hyun, Kim Youngjo, Lee Junseong
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Jan;68(Pt 1):m87 |
| doi: | 10.1107/S1600536811054134 | ||
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