In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525â (4)â à out of the square basal N2O2 least-squares plane. The complex mol-ecule is hydrogen bonded to the methanol solvent mol-ecule.
Chlorido[2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolato-κ(4) O,N,N',O']manganese(III) methanol monosolvate.
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作者:Lin Hui, Wang Jian-Gang, Shi Hua-Tian, Chen Qun, Zhang Qian-Feng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jun 19; 69(Pt 7):m404 |
| doi: | 10.1107/S1600536813016450 | ||
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