In the title compound, C14H15BrN2O2S, synthesized by the reaction of the corresponding phenacyl thio-cyanate with morpholine, the dihedral angle between the 1,3-thia-zole ring and the phenolic substituent ring is 23.46â (10)° as a result of the steric influence of the ortho-methyl group on the thia-zole ring. A strong intra-molecular phenolic O-Hâ¯N hydrogen bond is present in the mol-ecule. In the crystal, a weak C-Hâ¯Ophenol hydrogen bond gives rise to chains lying parallel to [20-1]. A short inter-molecular Brâ¯Omorpholine inter-action is also present [3.1338â (19)â à ].
4-Bromo-2-[5-methyl-2-(morpholin-4-yl)-1,3-thia-zol-4-yl]phenol.
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作者:Bahrin Lucian G, Hrib Cristian G, Birsa Lucian M
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jun 29; 69(Pt 7):o1170 |
| doi: | 10.1107/S1600536813017510 | ||
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