Hydro-flux synthesis and crystal structure of Tl(3)IO.

Single-crystals of thallium(I) iodide oxide Tl(3)IO were obtained as by-product in a hydro-flux synthesis at 473†K for 10†h. A potassium hydroxide hydro-flux with a water-base molar ratio of 1.6 and the starting materials TlNO(3), RhI(3) and Ba(NO(3))(2) was used, resulting in a few black needle-shaped crystals. X-ray diffraction on a single-crystal revealed the hexa-gonal space group P6(3)/mmc (No. 194) with lattice parameters a = 7.1512†(3)†à and c = 6.3639†(3)†à . Tl(3)IO crystallizes as hexa-gonal anti-perovskite (anti-BaNiO(3) type) and is thus structurally related to the alkali-metal halide/auride oxides M (3) XO (M = K, Rb, Cs; X = Cl, Br, I, Au). The oxygen atoms center thallium octa-hedra. The [OTl(6)] octa-hedra share trans faces, forming a linear chain along [001]. Twelve thallium atoms surround each iodine atom in an [ITl(12)] anti-cubocta-hedron. Thallium and iodine atoms together form a hexa-gonal close-sphere packing, in which every fourth octa-hedral void is occupied by oxygen.