The title compound, C23H22FN5S, exists in a trans conformation with respect to the methene C=C and the acyclic N=C bonds. The 1,2,4-triazole-5(4H)-thione ring makes dihedral angles of 88.66â (9) and 84.51â (10)°, respectively, with the indole and benzene rings. In the crystal, mol-ecules are linked by pairs of N-Hâ¯S hydrogen bonds, forming inversion dimers with an R 2 (2)(8) ring motif. The dimers are linked via C-Hâ¯Ï inter-actions, forming chains along [1-10]. The chains are linked via Ï-Ï inter-actions involving inversion-related triazole rings [centroid-centroid distance = 3.4340â (13)â à ], forming layers parallel to the ab plane.
Crystal structure of 4-({(1E,2E)-3-[3-(4-fluoro-phen-yl)-1-isopropyl-1H-indol-2-yl]allyl-idene}amino)-5-methyl-1H-1,2,4-triazole-5(4H)-thione.
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作者:Kulkarni Ajaykumar D, Rahman Md Lutfor, Mohd Yusoff Mashitah, Kwong Huey Chong, Quah Ching Kheng
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2015 | 起止号: | 2015 Oct 31; 71(Pt 11):1411-3 |
| doi: | 10.1107/S2056989015020101 | ||
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