In the centrosymmetric binuclear title compound, [Zn(2)Cl(4)(C(20)H(17)N(3))(2)], the coordination geometry of the Zn(II) ion can be described as a distorted ZnN(2)Cl(3) trigonal bipyramid (Ï = 0.89), arising from the N,N'-bidentate ligand, a terminal chloride ion and two bridging chloride ions. The N atoms occupy one axial and one equatorial site and the terminal chloride ion occupies an equatorial site. The dihedral angle between the pyridine and pyrazole rings is 12.8â (2)°. In the crystal, aromatic Ï-Ï stacking [centroid-centroid separations = 3.812â (3) and 3.848â (3)â à ] and C-Hâ¯Cl and C-Hâ¯Ï inter-actions help to establish the packing.
Di-μ-chlorido-bis-{chlorido[(R)/(S)-1,5-di-phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN]zinc(II)}.
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作者:Barceló-Oliver Miquel, Terrón Angel, GarcÃa-Raso Angel, Turel Iztok, Morell Marta
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jul 7; 66(Pt 8):m899-900 |
| doi: | 10.1107/S1600536810026127 | ||
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