The asymmetric unit of the title compound, [Zn(C(12)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2), contains one-half of the complex molecule and one NO(3) (-) anion. The Zn(II) ion displays a distorted tetra-gonal-pyramidal geometry with four N atoms from two chelating 4-amino-3,5-di-2-pyridyl-1,2,4-triazole (2-bpt) lig-ands in the basal plane and one water mol-ecule occupying the apical site. Another water mol-ecule at the opposite of the apical site has a weak inter-action with the Zn(II) ion [Zn-O = 2.852â (5)â Ã ]. The Zn(II) ion and the two water mol-ecules lie on a twofold rotation axis. An extensive system of hydrogen bonds involving the NH(2) groups of the 2-bpt ligands, water mol-ecules and nitrate anions links all residues into a three-dimensional network.
Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κN,N)diaqua-zinc(II) dinitrate.
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作者:Hua Jia, Gao Lu, Li Baiyan
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Aug 22; 65(Pt 9):m1106-7 |
| doi: | 10.1107/S1600536809032103 | ||
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