In the title compound, C17H17N3O3S, the thia-zole ring is nearly planar [maximum deviation = 0.015â (1)â à for the ring N atom] and the cyclo-pentane ring has a twist conformation. The mol-ecular conformation is stabilized by a hypervalent inter-action between the S atom and the ester group carbonyl O atom, with an Sâ¯O distance of 2.7931â (10)â à . In the crystal, C-Hâ¯O inter-actions generate chains of mol-ecules propagating along [110] and Ï-Ï stacking inter-actions [centroid-centroid distance = 3.4677â (7)â à ] between the thia-zole rings organize these chains into (001) layers.
Methyl (2Z)-2-{(2Z)-3-[(cyclo-pentyl-idene)amino]-4-oxo-2-phenyl-imino-1,3-thia-zol-idin-5-yl-idene}acetate.
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作者:Mague Joel T, Akkurt Mehmet, Mohamed Shaaban K, Hassan Alaa A, Albayati Mustafa R
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Feb 26; 70(Pt 3):o366-7 |
| doi: | 10.1107/S1600536814004048 | ||
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