In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octa-hedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate di-pyridyldi-amine ligand, two O-atom donors from one of the carboxyl-ate groups of the bidentate chelating adipate ligand and two water mol-ecules. In addition, there are three solvent water mol-ecules which are involved in both intra- and inter-unit O-Hâ¯O hydrogen-bonding inter-actions, which together with an amine-water N-Hâ¯O hydrogen bond produce a three-dimensional framework.
(Adipato-κ(2) O,O')di-aqua-[bis-(pyridin-2-yl-κN)amine]-cobalt(II) trihydrate.
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作者:Setifi Zouaoui, Setifi Fatima, Smith Graham, El-Ghozzi Malika, Rouag Djamil-Azzeddine, Avignant Daniel, Merazig Hocine
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 May 22; 69(Pt 6):m335-6 |
| doi: | 10.1107/S1600536813012981 | ||
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