Mol-ecules of the title amino-chalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26â (6)° between the 4-amino-phenyl and 2,4,5-trimeth-oxy-phenyl rings. The conformations of the three meth-oxy groups with respect to the benzene ring are slightly different. Two meth-oxy groups are almost coplanar with the attached benzene ring [C-O-C-C torsion angles of -1.45â (19) and 1.5â (2)°], while the third is (-)-synclinal with the attached benzene ring [C-O-C-C = -81.36â (17)°]. In the crystal structure, mol-ecules are stacked into columns along the b axis and mol-ecules in adjacent columns are linked by N-Hâ¯O hydrogen bonds into V-shaped double columns. Weak Ï-Ï inter-actions are also observed, with a centroid-centroid distance of 3.7532â (8)â à .
(E)-1-(4-Amino-phen-yl)-3-(2,4,5-trimeth-oxy-phen-yl)prop-2-en-1-one.
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作者:Fun Hoong-Kun, Kobkeatthawin Thawanrat, Ruanwas Pumsak, Chantrapromma Suchada
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jul 10; 66(Pt 8):o1973-4 |
| doi: | 10.1107/S1600536810026346 | ||
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