In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116â (6)â à . The second chloride anion is in the apical position and forms a longer Cu-Cl distance of 2.4655â (7)â à . Inter-molecular N-Hâ¯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Formula: see text]].
Dichlorido{N'-[(pyridin-2-yl)methyl-idene-κN]acetohydrazide-κN',O}copper(II).
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作者:Datta Amitabha, Sheu Shiann-Cherng, Liu Pei-Hsin, Huang Jui-Hsien
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Dec 1; 67(Pt 12):m1852 |
| doi: | 10.1107/S1600536811049671 | ||
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