In the crystal structure of the title compound, [Co(C(7)H(6)N(2))(2)(H(2)O)(4)]Cl(2), the Co(II) cation lies on an inversion center and is coordinated by two 2-amino-benzonitrile ligands and four water mol-ecules in a distorted octa-hedral geometry. The Cl(-) counter-anion links with the complex cations via O-Hâ¯Cl and N-Hâ¯Cl hydrogen bonding. Inter-molecular O-Hâ¯N hydrogen bonding links the complex cations, forming supra-molecular chains running along the b axis.
Bis(2-amino-benzonitrile)tetra-aqua-cobalt(II) dichloride.
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作者:Ru Zong-Ling, Wang Guo-Xi
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Nov 28; 65(Pt 12):m1688 |
| doi: | 10.1107/S1600536809050272 | ||
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