In the crystal structure of the title compound, 2C(10)H(7)NO(4)·C(14)H(13)N(3)O(2), the two independent acid mol-ecules are connected through strong O-Hâ¯N and O-Hâ¯O hydrogen bonds to the central mol-ecule of the anti-tubercular drug N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide. Two such trimolecular units related by an inversion centre inter-act through a pair of N-Hâ¯O hydrogen bonds, forming a 3 + 3 mol-ecular aggregate. The dihedral angle between the aromatic rings of the hydrazone mol-ecule is 1.99â (12)°. The crystal packing features weak C-Hâ¯O and Ï-Ï stacking inter-actions, with centroid-centroid distances of 3.8460â (19) and 3.8703â (13)â à .
2-(1,3-Dioxoisoindolin-2-yl)acetic acid-N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide (2/1).
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作者:NovakoviÄ Sladjana B, BogdanoviÄ Goran A, Mohamed Shaaban K, Albayati Mustafa R, Hameed Ayad S
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Oct 1; 68(Pt 10):o2897-8 |
| doi: | 10.1107/S1600536812038032 | ||
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