In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro-tris-(3,5-diphenyl-pyrazol-yl)borate ligand and a bidentate di-2-pyridyl-amine ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular N-Hâ¯Br and C-Hâ¯Br hydrogen bonds link the Ni complex cations and the Br(-) ions, forming a chain along the c axis.
(Di-2-pyridyl-amine-κN,N')[hydro-tris-(3,5-diphenyl-pyrazol-1-yl-κN)borato]nickel(II) bromide dichloro-methane monosolvate.
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作者:Harding David J, Harding Phimphaka, Adams Harry
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Apr 1; 67(Pt 4):m477-8 |
| doi: | 10.1107/S1600536811010233 | ||
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