The reaction of 2-amino-ethanol and iodo-penta-fluoro-benzene in the presence of K(2)CO(3) gave the title compound, C(8)H(6)F(4)INO, in high yield. The structure is characterized by double layers of mol-ecules linked by O-Hâ¯O and N-Hâ¯O hydrogen bonds, and linear C-Iâ¯F [Iâ¯F = 3.049â (2)â à ] and bent C-Iâ¯I [Iâ¯I = 3.9388â (7)â à ] inter-actions between pairs of nearly parallel iodo-tetra-fluoro-phenyl groups. No Oâ¯I or Nâ¯I halogen bonding is found.
2-(2,3,5,6-Tetra-fluoro-4-iodo-anilino)-ethanol.
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作者:Metrangolo Pierangelo, Meyer Franck, Pilati Tullio, Resnati Giuseppe
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2007 | 起止号: | 2007 Dec 6; 64(Pt 1):o211 |
| doi: | 10.1107/S1600536807064197 | ||
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