The title centrosymmetric mol-ecule, C(46)H(42)Si(2), is composed of a central benzene ring with buta-1,3-diynyl chains at positions 1 and 4. These chains are terminated by tert-butyl-diphenyl-silyl groups, hence the molecule is dumbbell in shape. The mol-ecules are connected via C-Hâ¯Ï inter-actions in the structure, so forming an undulating two-dimensional network in the bc plane. There is also a weak Ï-Ï inter-action involving centrosymmetrically related phenyl rings with a centroid-centroid distance of 3.8359â (11)â à .
1,4-Bis[4-(tert-butyl-diphenyl-silyl)buta-1,3-diyn-yl]benzene.
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作者:Thevenet Damien, Neier Reinhard, Stoeckli-Evans Helen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Mar 13; 66(Pt 4):o839-40 |
| doi: | 10.1107/S160053681000351X | ||
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