In the title compound, C18H10O8·4C2H6OS, the mid-point of the triple bond of the main mol-ecule is located on a special position, i.e. about an inversion center. The carboxyl groups are twisted slightly out of the planes of the aromatic rings to which they are attached, making dihedral angles of 24.89â (1) and 7.40â (2)°. The cystal packing features strong O-Hâ¯O hydrogen bonds, weaker C-Hâ¯O inter-actions and Oâ¯S contacts [3.0981â (11)â à ] and displays channel-like voids extending along the a-axis direction which contain the dimethyl sulfoxide solvent mol-ecules.
5,5'-(Ethyne-1,2-di-yl)diisophthalic acid dimethyl sulfoxide tetra-solvate.
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作者:Münch Alexander S, Katzsch Felix, Weber Edwin, Mertens Florian O R L
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 May 18; 69(Pt 6):o908-9 |
| doi: | 10.1107/S1600536813013068 | ||
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