The title compound, [Co(C(4)H(13)N(3))(2)][InCl(6)], was synthesized under hydro-thermal conditions. In the cation, the Co-N bond lengths lie in the range 1.967â (2)-1.9684â (15)â à . In the anion, the In(III) atom is coordinated by six Cl atoms resulting in a slightly distorted octa-hedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N-Hâ¯Cl hydrogen bonds between cations and anions consolidate the crystal packing.
Bis(diethyl-enetriamine)-cobalt(III) hexa-chloridoindate(III).
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作者:Wu Qihui, Chen Shangwen, Zhang Cailing, Zhi Xia, Chen Zelin
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jun 1; 67(Pt 6):m731 |
| doi: | 10.1107/S1600536811016758 | ||
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