The mol-ecule of the title Schiff base compound, C(16)H(15)N(3)O(5), obtained from a condensation reaction of 4-acet-oxy-3-meth-oxy-benzaldehyde and 4-nitro-phenyl-hydrazine, adopts an E geometry with respect to the C=N double bond. The mol-ecule is roughly planar, with the two benzene rings twisted slightly with respect to each other by a dihedral angle of 6.90â (9)°. In the crystal, inter-molecular N-Hâ¯O hydrogen bonds link centrosymmetrically related pairs of mol-ecules, forming dimers of R(2) (2)(22) graph-set motif. The dimers are further connected through slipped Ï-Ï inter-actions between symmetry-related benzene rings [centroid-centroid distance of 3.646â (1)â à , offset angle of 15.4°].
Methyl 2-meth-oxy-4-{[2-(4-nitro-phen-yl)hydrazinyl-idene]meth-yl}benzoate.
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作者:Zhao Zhen-Xin, Li He-Ping, Ma Bu-Wei
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Sep 30; 66(Pt 10):o2661 |
| doi: | 10.1107/S160053681003802X | ||
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