The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (-)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(-) and a water mol-ecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C-Hâ¯O, O-Hâ¯O, O-Hâ¯N and N-Hâ¯O hydrogen-bonding inter-actions and Ï-Ï stacking. The inter-molecular inter-actions of the synthesized compound were qu-anti-fied by Hirshfeld surface analysis.
Crystal structure of 2-(morpholino)ethyl-ammonium picrate monohydrate.
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作者:Chidambaranathan Balasubramanian, Sivaraj Settu, Selvakumar Shanmugam
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2023 | 起止号: | 2023 Jan 1; 79(Pt 1):8-13 |
| doi: | 10.1107/S2056989022011409 | ||
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