{2,7-Dimeth-oxy-8-[4-(propan-2-yl-oxy)benzo-yl]naphthalen-1-yl}[4-(propan-2-yl-oxy)phen-yl]methanone.

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作者:Sasagawa Kosuke, Takeuchi Ryo, Kusakabe Taro, Yonezawa Noriyuki, Okamoto Akiko
The title compound, C32H32O6, crystallized with two independent molecules in the asymmetric unit. Each molecule has essentially the same feature of non-coplanar aromatic rings whereby the two 4-isopropoxybenzoyl groups are twisted in a perpendicular manner to the naphthalene ring and oriented in the same direction (syn-orientation). The benzene rings of the aroyl groups make dihedral angles of 16.13†(7) and 25.31†(7)° in the two molecules. These benzene rings make dihedral angles of 88.38†(8) and 75.32†(7)° with the naphthalene ring system in one molecule, and 89.71†(7) and 82.11†(7)° in the other. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds, forming a three-dimensional network. In one independent molecule, the 2-propyl groups of both isoprop-oxy groups are disordered over two positions with site occupancies of 0.512†(3) and 0.488†(3).

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