The title compound, C32H32O6, crystallized with two independent molecules in the asymmetric unit. Each molecule has essentially the same feature of non-coplanar aromatic rings whereby the two 4-isopropoxybenzoyl groups are twisted in a perpendicular manner to the naphthalene ring and oriented in the same direction (syn-orientation). The benzene rings of the aroyl groups make dihedral angles of 16.13â (7) and 25.31â (7)° in the two molecules. These benzene rings make dihedral angles of 88.38â (8) and 75.32â (7)° with the naphthalene ring system in one molecule, and 89.71â (7) and 82.11â (7)° in the other. In the crystal, mol-ecules are linked via C-Hâ¯O hydrogen bonds, forming a three-dimensional network. In one independent molecule, the 2-propyl groups of both isoprop-oxy groups are disordered over two positions with site occupancies of 0.512â (3) and 0.488â (3).
{2,7-Dimeth-oxy-8-[4-(propan-2-yl-oxy)benzo-yl]naphthalen-1-yl}[4-(propan-2-yl-oxy)phen-yl]methanone.
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作者:Sasagawa Kosuke, Takeuchi Ryo, Kusakabe Taro, Yonezawa Noriyuki, Okamoto Akiko
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Mar 1; 69(Pt 3):o444-5 |
| doi: | 10.1107/S1600536813004959 | ||
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