The title compound, C(15)H(13)ClO(2)S, comprises (4-chloro-phen-yl)sulfanyl, benzaldehyde and meth-oxy residues linked at a chiral methine-C atom (the crystal is racemic). A twist in the methine-C-C(carbon-yl) bond [O-C-C-O torsion angle = 19.3â (7)°] leads to a dihedral angle of 22.2â (5)° between the benzaldehyde and methine+meth-oxy residues. The chloro-benzene ring is folded to lie over the O atoms, with the dihedral angle between the benzene rings being 42.9â (2)°. In the crystal, the carbonyl-O atom accepts two C-Hâ¯O inter-actions with methyl- and methine-C-H atoms being the donors. The result is an helical supra-molecular chain aligned along the c axis; chains pack with no directional inter-actions between them. An analysis of the Hirshfeld surface points to the important contributions of weak Hâ¯H and Câ¯C contacts to the mol-ecular packing.
2-[(4-Chloro-phen-yl)sulfan-yl]-2-meth-oxy-1-phenyl-ethan-1-one: crystal structure and Hirshfeld surface analysis.
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作者:Caracelli Ignez, Zukerman-Schpector Julio, Traesel Henrique J, Olivato Paulo R, Jotani Mukesh M, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2018 | 起止号: | 2018 Apr 27; 74(Pt 5):703-708 |
| doi: | 10.1107/S2056989018006072 | ||
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