In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N'-chelated by two 2,2'-diamino-4,4'-bi-1,3-thia-zole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octa-hedral geometry. One of the uncoordinated water mol-ecules is close to an inversion center and is disordered equally over two sites. Intra-molecular N-Hâ¯N and N-Hâ¯O inter-actions are present. An extensive hydrogen-bonding network of types N-Hâ¯O, O-Hâ¯O, O-Hâ¯N and O-Hâ¯S consolidates the crystal structure.
Bis(2,2'-diamino-4,4'-bi-1,3-thia-zole-κN,N)bis-(nitrato-κO)lead(II) dihydrate.
双(2,2'-二氨基-4,4'-双-1,3-噻唑-ΎoN,N)二-(硝酸盐-ΎoO)铅(II)二水合物
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作者:Liu Bing-Xin, Xu Duan-Jun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Jul 29; 65(Pt 8):m1002-3 |
| doi: | 10.1107/S1600536809029638 | ||
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