(η-Cyclo-octa-1,5-diene)diiodidoplatinum(II).

(α·-环辛-1,5-二烯)二碘铂(II)

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作者:Thibault Marie-Hélène, Fontaine Frédéric-Georges
The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclo-octa-diene ring, is similar to its Cl and Br ortho-rhom-bic homologues. The observed Pt-I bond distances of 2.6094†(5) and 2.6130†(5)†à are in the expected range for PtI(2) complexes. The C=C double bonds in the mol-ecule differ significantly [1.373†(10) and 1.403†(10)†à ]. As expected for a platinum(II) complex, the Pt(II) atom is in a square-planar environment (ΣPt(α)= 359.71°).

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