Poly[[diaqua-hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate].

聚[[二水合半-α(4)-草酸根-α(2)-草酸根-镨(III)]一水合物]

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作者:Yang Ting-Hai, Chen Qiang, Zhuang Wei, Wang Zhe, Yue Bang-Yi
In the title complex, {[Pr(C(2)O(4))(1.5)(H(2)O)(2)]·H(2)O}(n), the Pr(III) ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr-O coordination from tetra-dentate oxalate ligands forms a three-dimensional structure. The compound crystallized as a monohydrate, the water mol-ecule occupying space in small voids and being secured by O-H⋯O hydrogen bonding as an acceptor from ligand water H atoms and as a donor to oxalate O-acceptor sites.

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