In the title compound, [Y(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(C(12)H(8)N(2))(2)]·2H(2)O, the Y(III) ion lies on a twofold rotation axis and exhibits a distorted square-anti-prismatic coordination geometry. It is chelated by two 1,10-phenanthroline ligands, a 2,4-dioxo-1,2,3,4-tetra-hydro-pyrimidine-5-carboxyl-ate mono-anion and a 4-oxido-2-oxo-1,2-dihydro-pyrimidine-5-carboxyl-ate dianion. The H atom involved in an N-Hâ¯N hydrogen bond between the 1,2-dihydro-pyrimidine units has half occupancy and is disordered around a twofold rotation axis.
(2,4-Dioxo-1,2,3,4-tetra-hydro-pyrimi-dine-5-carboxyl-ato-κO,O)(4-oxido-2-oxo-1,2-dihydro-pyrimidine-5-carboxyl-ato-κO,O)bis-(1,10-phenanthroline-κN,N')yttrium(III) dihydrate.
(2,4-二氧-1,2,3,4-四氢-嘧啶-5-羧基-αO,O)(4-氧化-2-氧代-1,2-二氢-嘧啶-5-羧基-α-O,O)双-(1,10-菲咯啉-γN,N')钇(III)二水合物
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作者:Xiong Wei, Xing Huihui, Su Yan, Chen Zilu
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Aug 16; 64(Pt 9):m1166-7 |
| doi: | 10.1107/S1600536808025701 | ||
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