In the tetranuclear centrosymmetric title compound, [Pb(4)(NO(3))(8)(C(11)H(10)N(2))(4)], irregular PbN(2)O(5) and PbN(2)O(4) coordination polyhedra occur. The hepta-coordinated lead(II) ion is bonded to two bidentate and one monodentate nitrate ion and one bidentate 6-methyl-2,2'-bipyridine (mbpy) ligand. The six-coordinate lead(II) ion is bonded to one bidentate and two monodentate nitrate anions and one mbpy ligand. In the crystal, bridging nitrate anions lead to infinite chains propagating in [111]. A number of C-Hâ¯O hydrogen bonds may stabilize the structure.
Tetra-kis(6-methyl-2,2'-bipyridine)-1κN,N';2κN,N';3κN,N';4κN,N'-tetra-μ-nitrato-1:2κO:O';2:3κO:O',O'';2:3κO,O':O'';3:4κO:O'-tetra-nitrato-1κO,O';4κO,O'-tetra-lead(II).
四-kis(6-甲基-2,2'-联吡啶)-1°N,N';2°N,N';3°N,N';4°N,N'-四-1/4-硝酸盐-1:2 ºO:O';2:3ºO:O',O'';2:3ºO,O':O'';3:4ºO:O'-四硝酸盐-1ºO,O';4ºO,O'-四铅(II)
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作者:Ahmadi Roya, Kalateh Khadijeh, Alizadeh Robabeh, Khoshtarkib Zeinab, Amani Vahid
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Sep 5; 65(Pt 10):m1169-70 |
| doi: | 10.1107/S160053680903459X | ||
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