In the centrosymmetric dinuclear title Ag(I) compound, [Ag2(C6H6N2O)4](NO3)2, the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl-amine mol-ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound mol-ecules via O-Hâ¯O hydrogen bonds, generating a chain running along the a-axis direction.
Bis[μ-(E)-N-(pyridin-3-yl-methyl-idene)hy-droxy-amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis-{[(E)-N-(pyridin-3-yl-methyl-idene-κN)hy-droxy-amine]-silver(I)} dinitrate.
双[μ-(E)-N-(吡啶-3-基-甲基-亚基)羟基-胺]-γ(2) N (1):N (3);γ(2) N (3):N (1)-二-{[(E)-N-(吡啶-3-基-甲基-亚基-γN)羟基胺]-银(I)}二硝酸盐
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作者:Gao Shan, Ng Seik Weng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Dec 1; 68(Pt 12):m1547 |
| doi: | 10.1107/S1600536812045898 | ||
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