In the title compound, C34H28N2S2, the central imidazole ring (r.m.s. deviation = 0.0015â à ) forms dihedral angles of 55.7â (3), 17.94â (11) and 86.27â (11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupancy ratio = 0.647â (2):0.353â (2)]. The chiral centre maintains the S configuration of the l-phenyl-alaninol starting material. Intra- and inter-molecular C-Hâ¯S hydrogen bonds involving the disordered thienyl ring are observed.
(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl-sulfan-yl)propan-2-yl]-2-(thio-phen-2-yl)-1H-imidazole.
(S)-4,5-二苯基-1-[1-苯基-3-(苯硫基)丙-2-基]-2-(噻吩-2-基)-1H-咪唑
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作者:Gao Jie, Wang Hongyan, Yang Liangru, Xiao Yongmei, Mao Pu
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Nov 30; 69(Pt 12):o1858 |
| doi: | 10.1107/S1600536813032066 | ||
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