In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57â (1)°. In the crystal, mol-ecules are linked by weak N-Hâ¯Cl hydrogen bonds into layers parallel to the bc plane. Ï-Ï inter-actions with centroid-centroid distances in the range 3.4452â (8)-3.8074â (8)â à are also observed.
[2-(1H-Benzimidazol-2-yl-κN)aniline-κN]dichloridozinc.
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作者:Eltayeb Naser Eltaher, Teoh Siang Guan, Chantrapromma Suchada, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Aug 1; 67(Pt 8):m1062-3 |
| doi: | 10.1107/S1600536811026572 | ||
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