The title di-chloro-cobalt(II) complex, trans-[CoCl(2)(1)(2)] [1 = 8-(benzyl-sulfanyl)-quinoline, C(16)H(13)NS], has a central Co(II) atom (site symmetry ) that exhibits a distorted octa-hedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak inter-molecular C-Hâ¯Ï inter-actions between the 8-(benzyl-sulfanyl)-quinoline ligands, forming a chain extending along the a-axis direction.
trans-Bis[8-(benzyl-sulfan-yl)quinoline-κ(2) N,S]di-chlorido-cobalt(II).
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作者:Kodama Shintaro, Bunno Kazuki, Nomoto Akihiro, Ogawa Akiya
| 期刊: | IUCrdata | 影响因子: | 0.000 |
| 时间: | 2021 | 起止号: | 2021 Oct 4; 6(Pt 10):x210992 |
| doi: | 10.1107/S2414314621009925 | ||
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