trans-Bis[8-(benzyl-sulfan-yl)quinoline-κ(2) N,S]di-chlorido-cobalt(II).

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作者:Kodama Shintaro, Bunno Kazuki, Nomoto Akihiro, Ogawa Akiya
The title di-chloro-cobalt(II) complex, trans-[CoCl(2)(1)(2)] [1 = 8-(benzyl-sulfanyl)-quinoline, C(16)H(13)NS], has a central Co(II) atom (site symmetry ) that exhibits a distorted octa-hedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak inter-molecular C-H⋯π inter-actions between the 8-(benzyl-sulfanyl)-quinoline ligands, forming a chain extending along the a-axis direction.

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