In the title com-pound, C(13)H(14)N(2)O(3), the dihydropyridazine ring (r.m.s. deviation = 0.166â à ) has a screw-boat conformation. The dihedral angle between its mean plane and the benzene ring is 0.77â (12)°. In the crystal, inter-molecular O-Hâ¯O hydrogen bonds generate C(5) chains and N-Hâ¯O hydrogen bonds produce R (2) (2)(8) motifs. These types of inter-actions lead to the formation of layers parallel to (12). The three-dimensional network is achieved by C-Hâ¯O inter-actions, including R (2) (4)(8) motifs. Inter-molecular inter-actions were additionally investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots. The most significant contributions to the crystal packing are by Hâ¯H (43.3%), Hâ¯C/Câ¯H (19.3%), Hâ¯O/Hâ¯O (22.6%), Câ¯N/Nâ¯C (3.0%) and Hâ¯N/Nâ¯H (5.8%) contacts. C-Hâ¯Ï inter-actions and aromatic Ï-Ï stacking inter-actions are not observed.
Crystal structure and Hirshfeld surface analysis of (E)-6-(4-hy-droxy-3-meth-oxy-styr-yl)-4,5-di-hydro-pyridazin-3(2H)-one.
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作者:Daoui Said, Baydere Cemile, El Kalai Fouad, Saddik Rafik, Dege Necmi, Karrouchi Khalid, Benchat Noureddine
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2019 | 起止号: | 2019 Oct 31; 75(Pt 11):1734-1737 |
| doi: | 10.1107/S2056989019014130 | ||
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