The title compound, C(17)H(13)BrN(4)O(5), was synthesized by a Cu(2)Br(2)-catalysed Meldal-Sharpless reaction between 4-nitro-phen-oxy-acetic acid propargyl ether and para-bromo-phenyl-azide, and characterized by X-ray structure determination and (1)H NMR spectroscopy. The mol-ecules, with a near-perpendicular orientation of the bromo-phenyl-triazole and nitro-phen-oxy-acetate fragments, are connected into a three-dimensional network by inter-molecular C-Hâ¯O and C-Hâ¯N hydrogen bonds (confirmed by Hirshfeld surface analysis), Ï-Ï and Br-Ï inter-actions.
Synthesis, crystal structure and Hirshfeld surface analysis of [1-(4-bromo-phen-yl)-1H-1,2,3-triazol-4-yl]methyl 2-(4-nitro-phen-oxy)acetate.
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作者:Hakimov Muminjon, Khozhimatova Shakhnoza, Ortikov Ilkhomjon, Abdugafurov Ibragimdjan, Tojiboev Akmaljon
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2024 | 起止号: | 2024 Jul 31; 80(Pt 8):910-912 |
| doi: | 10.1107/S2056989024007436 | ||
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