The tricyclic core in the title compound, C(26)H(34)O(4)Si(2), shows disorder of the furan ring and deviates slightly from planarity, with the largest displacement from the least-squares plane [0.166â (2)â à ] for the major disordered part of the methine C atom. To this C atom the likewise disordered vinyl group is attached, lying nearly perpendicular to the tricyclic core. In the crystal, mutual C-Hâ¯Ï inter-actions between the methine group of the furan ring and the central ring of the tricyclic core of an adjacent mol-ecule lead to inversion-related dimers.
6-[(tert-Butyl-dimethyl-sil-yl)-oxy]-3-ethenyl-7-meth-oxy-4-[(tri-methyl-sil-yl)ethyn-yl]naphtho-[2,3-c]furan-1(3H)-one.
阅读:2
作者:Weil Matthias, Kremsmayr Thomas, Mihovilovic Marko D
| 期刊: | IUCrdata | 影响因子: | 0.000 |
| 时间: | 2020 | 起止号: | 2020 Feb 21; 5(Pt 2):x200224 |
| doi: | 10.1107/S2414314620002242 | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
