In the title compound, [Zn(C48H36N4O4)]·2CH2Cl2, the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di-chloro-methane solvent mol-ecule. The unique meth-oxy-substituted benzene rings form dihedral angles of 59.38â (6) and 66.77â (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282â à ) of the atoms in the porphyrin core. The packing is characterized by close contacts between the Zn(II) ion and two symmetry-related mol-ecules through the O atoms of a meth-oxy-phenyl group [Znâ¯O = 2.694â (2)â à ], forming a two-dimensional network parallel to (100).
[5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinato]zinc di-chloro-methane disolvate.
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作者:McGill Sean, Nesterov Vladimir N, Gould Stephanie L
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jul 24; 69(Pt 8):m471 |
| doi: | 10.1107/S1600536813019338 | ||
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