In the title compound, C12H15IO7, the 3,4-di-hydro-2H-pyran ring is in a distorted half-boat conformation with the atom bearing the acet-yloxy group adjacent to the C atom bearing the methyl-acetate group lying 0.633â (6)â à above the plane of the remaining ring atoms (r.m.s. deviation = 0.0907â à ). In the crystal, mol-ecules are linked into a supra-molecular chain along the a axis through two C-Hâ¯O inter-actions to the same acceptor carbonyl O atom; these chains pack with no specific inter-molecular inter-actions between them.
Crystal structure of [(2R,3R,4S)-3,4-bis(acet-yloxy)-5-iodo-3,4-di-hydro-2H-pyran-2-yl]methyl acetate.
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作者:Zukerman-Schpector Julio, Caracelli Ignez, Stefani Hélio A, Shamim Anwar, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2015 | 起止号: | 2015 Jan 1; 71(Pt 1):o53-4 |
| doi: | 10.1107/S205698901402564X | ||
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