In the title compound, C17H15NO4, the conformation about the C=C double bond [1.348â (2)â à ] is E with the ketone group almost co-planar [C-C-C-C torsion angle = 7.2â (2)°] but the phenyl group twisted away [C-C-C-C = 160.93â (17)°]. The terminal aromatic rings are almost perpendicular to each other [dihedral angle = 81.61â (9)°] giving the mol-ecule an overall U-shape. The crystal packing feature benzene-C-Hâ¯O(ketone) contacts that lead to supra-molecular helical chains along the b axis. These are connected by Ï-Ï inter-actions between benzene and phenyl rings [inter-centroid distance = 3.6648â (14)â à ], resulting in the formation of a supra-molecular layer in the bc plane.
Crystal structure of (3E)-3-[(4-nitro-phen-oxy)-meth-yl]-4-phenyl-but-3-en-2-one.
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作者:Zukerman-Schpector Julio, Maganhi Stella H, Moran Paulo J S, de Paula Bruno R S, Nucci Paulo R Jr, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Aug 16; 70(Pt 9):o1020-1 |
| doi: | 10.1107/S1600536814018327 | ||
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