Abstract
A lattice metric singularity occurs when unit cells defining two (or more) lattices yield the identical set of unique calculated d-spacings. The minerals Mawsonite and Chatkalite are of especial interest as both are characterized by tetragonal unit cells that correspond to the second member of a quaternary lattice metric singularity. This singularity includes lattices that are Cubic I, Tetragonal P, Orthorhombic F, and Orthorhombic P. The Mawsonite and Chatkalite lattices are unique in that they are highly specialized. In each case: (1) the determinative c/a ratio is very near 1/√2, (2) the symmetrical scalars of the reduced form [ a · a : b · b : c · c = 1:2:2] have greater specialization than required for the given reduced form type, (3) the tetragonal lattice has derivative lattices of higher symmetry, and (4) the powder pattern is highly compressed. Mawsonite and Chatkalite serve as exemplar-type compounds. Their tetragonal structure has important implications in structure determination using powder diffraction data. First, any cubic I lattice - established solely on the basis of indexing procedures - may actually be tetragonal or orthorhombic. Second, in establishing the lattice of an unknown, results from powder data indexing require routine confirmation by other techniques (e.g., single crystal, optical, etc.).