Abstract
We report the growth and nanoscale luminescence characteristics of 8-hydroxyquinolinato aluminum (Alq₃) with a crystalline hexagonal column morphology. Pristine Alq₃ nanoparticles (NPs) were prepared using a conventional reprecipitation method. Crystal hexagonal columns of Alq₃ were grown by using a surfactant-assisted self-assembly technique as an adjunct to the aforementioned reprecipitation method. The formation and structural properties of the crystalline and non-crystalline Alq₃ NPs were analyzed with scanning electron microscopy and X-ray diffraction. The nanoscale photoluminescence (PL) characteristics and the luminescence color of the Alq₃ single NPs and their crystal microwires (MWs) were evaluated from color charge-coupled device images acquired using a high-resolution laser confocal microscope. In comparison with the Alq₃ NPs, the crystalline MWs exhibited a very bright and sharp emission. This enhanced and sharp emission from the crystalline Alq₃ single MWs originated from effective π-π stacking of the Alq₃ molecules due to strong interactions in the crystalline structure.