2-(4-Chloro-phen-yl)acetic acid-2-{(E)-[(E)-2-(2-pyridyl-methyl-idene)hydrazin-1-yl-idene]meth-yl}pyridine (1/1)

2-(4-氯苯基)乙酸-2-{(E)-[(E)-2-(2-吡啶基亚甲基)肼-1-基亚甲基]甲基}吡啶 (1/1)

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作者:Hadi D Arman, Trupta Kaulgud, Edward R T Tiekink

Abstract

In the crystal of the title 1:1 adduct, C(8)H(7)ClO(2)·C(12)H(10)N(4), the components are linked by an O-H⋯N hydrogen bond between the carb-oxy-lic acid and one of the pyridine N atoms. In the acid, the carb-oxy-lic acid group is approximately normal to [dihedral angle = 72.9 (2)°] but twisted with respect to the plane through the benzene ring [C-C-C-O torsion angle = 25.4 (5)°]. The base is roughly planar [dihedral angle between rings = 12.66 (15)°; r.m.s. deviation of the 16 non-H atoms = 0.107 Å] and the conformations about both imine bonds are E. The dimeric aggregates are linked into a supra-molecular layer in the ab plane by C-H⋯O inter-actions.

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