Abstract
Exhaled acetone is one of the representative biomarkers for the noninvasive diagnosis of type-1 diabetes. In this work, we have applied a facile two-step chemical bath deposition method for acetone sensors based on α-Fe(2)O(3)/SnO(2) hybrid nanoarrays (HNAs), where one-dimensional (1D) FeOOH nanorods are in situ grown on the prefabricated 2D SnO(2) nanosheets for on-chip construction of 1D/2D HNAs. After annealing in air, ultrafine α-Fe(2)O(3) nanorods are homogenously distributed on the surface of SnO(2) nanosheet arrays (NSAs). Gas sensing results show that the α-Fe(2)O(3)/SnO(2) HNAs exhibit a greatly enhanced response to acetone (3.25 at 0.4 ppm) at a sub-ppm level compared with those based on pure SnO(2) NSAs (1.16 at 0.4 ppm) and pure α-Fe(2)O(3) nanorods (1.03 at 0.4 ppm), at an operating temperature of 340°C. The enhanced acetone sensing performance may be attributed to the formation of α-Fe(2)O(3)-SnO(2) n-n heterostructure with 1D/2D hybrid architectures. Moreover, the α-Fe(2)O(3)/SnO(2) HNAs also possess good reproducibility and selectivity toward acetone vapor, suggesting its potential application in breath acetone analysis.