Abstract
Polymer inclusion membranes (PIMs) have been reported to be useful for the selective separation of numerous metal ions, with multiple applications in areas such as analytical chemistry, water quality monitoring, water treatment, and metal recovery. This review aims to update the recent advancements related to PIM technology in metal ion separation, with a particular emphasis on environmentally friendly production and applications. PIMs have many advantages over classical liquid-liquid extraction, such as excellent selectivity, ease of use with simultaneous extraction and back-extraction, stability, and reusability. PIMs typically consist of a base polymer, a carrier, and, if necessary, a plasticizer, and can therefore be tailored to specific analytes and specific matrices. Consequently, numerous studies have been carried out to develop PIMs for specific applications. In analytical chemistry, PIMs have been used mostly for analyte preconcentration, matrix separation, speciation analysis, and sensing. They can be used as passive sampling tools or integrated into automated water monitoring systems. PIMs are also widely studied for the extraction and purification of valuable metals in the frame of the circular economy, as well as for wastewater treatment. Even if they are a greener alternative to classical metal extraction, their production still requires petroleum-based polymers and toxic and volatile solvents. In recent years, there has been a clear trend to replace classical polymers with biodegradable and bio-sourced polymers and to replace the production of PIMs using toxic solvents with those based on green solvents or without solvents. According to the published literature, environmentally friendly PIM-based techniques are a highly recommended area of future research for metal ion separation directed toward a wide range of applications.